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Fmoc-D-Thr[Psi(Me,Me)Pro]-OH
Chemischer Name: (4R,5S)-3-{[(9H-fluoren-9-yl)methoxy]carbonyl}-2,2,5-trimethyl-1,3-oxazolidine-4-carboxylic acid
- Art-Nr.:PSI1650
- CAS Nr.:159681-93-3
- Formel:C22H23NO5
- Molare Masse:381,43 g/mol
- Reinheit:min.99%
Startet von 95,00 €
description
D-Threonine-derived Pseudoproline monomer for SPPS. This building-block can be successfully coupled with many amino-acids using modern coupling techniques avoiding the need for pseudoproline dipeptides and giving the possibility to introduce pseudoprolines in peptides containing non-natural or rare amino-acids.
references
Solid-Phase Synthesis of an “Inaccessible” hGH-Derived Peptide Using a Pseudoproline Monomer and SIT-Protection for Cysteine; S. R. Manne, A. Chakraborty, K. Rustler, T. Bruckdorfer, B. G. de la Torre, F. Albericio; ACS Omega 2022; 7(32): 28487–28492. https://doi.org/10.1021/acsomega.2c03261
Scope and limitations of pseudoprolines as individual amino acids in peptide synthesis; D. A. Senko, N. D. Timofeev, I. E. Kasheverov, I. A. Ivanov; Amino Acids 2021; 53: 665–671. https://doi.org/10.1007/s00726-021-02973-1
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Related news
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News Amino Acids Building BlocksAcylation Efficiencies on Ser and Thr Pseudoproline Monomers
In two joint studies together with Prof. F. Albericio we investigated the coupling efficiencies of Ser and Thr pseudoproline monomers and their use
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