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Chemical name: N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-aspartic acid alpha-(2-phenylisopropyl ester) // Synonyms: Fmoc-Asp-O-2PhiPr, Fmoc-Asp-OPis, (S)-3-(((9H-fluoren-9-yl)methoxy)carbonylamino)-4-oxo-4-(2-phenylpropan-2-yloxy)butanoic acid
|Molecular weight:||473,52 g/mol|
An Aspartic acid building block with free side chain and PP protected alpha-carboxylic acid function. The 2-phenylisopropyl protecting group can be deprotected with 1% TFA in dichloromethane. PP protected amino acids are also less prone towards aspartamide formation.
C.Yue et al.; Tetrahedron Lett. 1993; 34: 323.
F.Dick et al.; Peptides 1996; Proceedings of the 24th European Peptide Symposium Edinborough, Scotland, p.339.
R.Ramage, R.Epton, eds. Mayflower Scientific Ltd., England (1998)
M.Mergler et al.; J.Pept.Sci. 2003; 9: 36.
S.M.Ocampo et al.; Org.Lett. 2005; 7: 4349.
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