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Fmoc-AAHA(Boc)-OH (S)
Chemical name: (S)-2-(Fmoc-amino)-6-(Boc-aminoxy)hexanoic acid // Synonyms: (S)-Fmoc-AAHA(Boc)-OH, Fmoc-(S)-AAHA(Boc)-OH, Fmoc-AAHA(Boc)-OH, (N-alpha-(9-Fluorenylmethyloxycarbonyl)-amino)-6-((t-butyloxycarbonyl)-aminooxy)hexanoic acid,(S)-2-((((9H-fluoren-9-yl)methoxy)carbo nyl)amino)-6-(((tert-butoxycarbonyl)amino)oxy)hexa
- Product code:FAA8450
- CAS No.:357278-11-6
- Formula:C26H32N2O7
- Molecular weight:484.54 g/mol
Starting at $227.50
description
The aminooxy group exhibits greater nucleophilicity than the corresponding primary amino group. It is therefore considered to react chemoselectively with carbonyl compounds by forming a kinetically stable oxime bond, which is more stable than an imine bond.
references
Synthesis of (S)-(+)-2-Amino-6-(Aminooxy)-hexanoic acid; M. Adamczyk, R. E. Reddy; Synth. Commun. 2001; 31: 579-586. https://doi.org/10.1081/SCC-100000585.
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