Boc-L-Pro(4-OPh)-OH (2S,4R)

Chemical name: (2S,4R)-1-t-Butyloxycarbonyl-4-phenoxy-pyrrolidine-2-carboxylic acid // Synonyms: (2S,4R)-Boc-4-phenoxy-pyrrolidine-2-carboxylic acid

Product code:BAA3460
CAS No.:147267-15-0
Formula:C16H21NO5
Molecular weight:307,34 g/mol
Grouped product items
Qty Packing unit Price SKU
1 g
$405.00
BAA3460.0001
5 g
$1,620.00
BAA3460.0005
New
description

Selective cleavage of the allyl and (allyloxy)carbonyl groups through palladium-catalyzed hydrostannolysis with tributyltin hydride. Application to the selective protection-deprotection of amino acid derivatives and in peptide synthesis; O. Dangles, F. Gu ibe, G. Balavoine, S. Lavielle and A. Marquet; The Journal of Organic Chemistry 1987; 52: 4984-4993. doi:10.1021/jo00231a027

Allylic protecting groups and their use in a complex environment part II: Allylic protecting groups and their removal through catalytic palladium -allyl methodology; F. Guib; Tetrahedron 1998; 54: 2967-3042. doi:http://dx.doi.org/10.1016/S0040-4020(97)10383-0

Mild non-transition metal catalyzed deprotection of N-allyloxycarbonyl amines; R. H. Szumigala Jr, E. Onofiok, S. Karady, J. D. Armstrong Iii and R. A. Miller; Tetrahedron letters 2005; 46: 4403-4405. doi:http://dx.doi.org/10.1016/j.tetlet.2005.04.064

Highly efficient removal of allyloxycarbonyl (Alloc) function provides a practical orthogonal protective strategy for carbohydrates; G. H. Zong, S. Q. Yan, X. M. Liang, J. J. Zhang, D. Q. Wang and F. Z. Kong; Chinese Chemical Letters 2009; 20: 127-130. doi:http://dx.doi.org/10.1016/j.cclet.2008.11.002

The Allyloxycarbonyl (Aloc) Moiety—Conversion of an Unsuitable into a Valuable Amino Protecting Group for Peptide Synthesis; H. Kunz and C. Unverzagt; Angewandte Chemie International Edition in English 1984; 23: 436-437. doi:10.1002/anie.198404361


Bulk or large quantity order?

Do you need larger quantities for your development or production?

Do you need further information of this product?

get in contact

Quick contact

Please send me more information about

We found other products you might like!
Structure image for Fmoc-L-Pro(4-OBzl)-OH (2S,4R)
Fmoc-L-Pro(4-OBzl)-OH (2S,4R)

Starting at Please inquire

Structure image for Boc-L-Pro(4-OPh)-OH (2S,4S)
Boc-L-Pro(4-OPh)-OH (2S,4S)

Starting at $202.50

Structure image for Fmoc-L-Pro(4-OPh)-OH (2S,4S)
Fmoc-L-Pro(4-OPh)-OH (2S,4S)

Starting at $337.50

Structure image for Fmoc-L-Pro(4-OPh)-OH (2S,4R)
Fmoc-L-Pro(4-OPh)-OH (2S,4R)

Starting at $607.50